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 Form 4 Chemistry: Energy changes in chemical and physical processes lessons

Meaning of exothermic reactions with examples

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Answer Text:
Exothermic reactions:
- Are reactions accompanied by a rise in temperature and energy is liberated to the surroundings.
- The enthalpy change is normally negative, since heat of reactants (H1) is normally higher than heat of products (H2).
- Thus,H2-H1 gives a negative value since H1 is higher thanH2.
Exothermic reactions can be represented graphically as follows;-
figchanges22720201133.JPG
- In exothermic reactions H2 is lower than H1.
Examples:
(i). Manufacture of ammonia in the Haber process;
i.e. N2(g)+3H2(g)2NH3(g);ΔH=-46Kjmol-
(ii) Dissolving sodium hydroxide pellets in water,
-The temperature of the resulting NaOH(aq) is higher than the temperature of water at room temperature.
-This implies the internal temperature of products is lower than the reactants‟ original temperature.
-Thus (H products – H reactants) =-ve value, an exothermic reaction.


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